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Composite biocompatible basado en aleación de titanio con revestimiento de carbono vítreo para endoprótesis

Resumen

Tipo:
Oferta Tecnológica
Referencia:
TOBG20181122001
Publicado:
06/12/2018
Caducidad:
07/12/2019
Resumen:
Un instituto de investigación búlgaro ha desarrollado un nuevo composite biocompatible basado en titanio con revestimiento de carbono vítreo. Gracias a sus propiedades de compatibilidad biológica y resistencia a la corrosión bioquímica, este material está indicado para la producción de endoprótesis. La impresión 3D con polvo de titanio ofrece la oportunidad de producir un implante individual conforme a la forma y a las dimensiones del órgano dañado. El revestimiento de carbono vítreo se adhiere perfectamente a la superficie de titanio y puede pulirse para obtener la rugosidad deseada. Este revestimiento se tolera muy bien por los tejidos adyacentes. El instituto de investigación busca socios industriales e investigadores con el fin de establecer acuerdos de cooperación técnica o investigación.

Details

Tittle:
Composite bio-compatible material on the basis of titanium alloys and vitreous carbon coating intended for endoprosthesis
Summary:
A Bulgarian research institute has developed an innovative composite bio-compatible material on titanium basis with glassy (vitreous) carbon coating. It is intended for production of endoprosthesis due to its biological compatibility and resistance to biochemical corrosion. The researchers are seeking industrial or research partners for technical cooperation or research cooperation agreements.
Description:
The Bulgarian research unit conducts R-Y-D in metal science, specialised coatings, heat treatment, casting, crystallisation, structure and properties of metals, alloys and composites and nano-materials, plasticity modelling, destruction of materials, etc. They have excellent experience in international collaboration and project implementation.

Titanium alloys are the basis for the production of endo-prostheses as titanium is a bio-compatible material for the human body. After a stay in the human body it is possible that part of the Al and V present in the titanium alloy can be partially ionized and corrosion and loosening of the bond between the titanium implant and the human bone may occur. Deposition of layer of vitreous (nascent) carbon, which is also proven to be bio compatible, on the titanium matrix neutralises the biochemical corrosion.
The fabrication of the hip joint or other endo-prosthesis can be made by traditional metal working of titanium. On the other hand, additive manufacturing may be used to prepare implant for each individual case. The 3-D printer with titanium powder will follow the shape and the dimensions of the damaged organ to produce an individual implant.

The different use of the implant needs different surface smoothness, e.g. the stem of the hip joint prosthesis is preferred to be more rough for better intergrowth with the bone whilst the femoral head must be polished to decrease the friction with the acetabular shell and polyethylene insert. The surface roughness is achieved by plasma spraying of titanium particles and the smoothness - by mechanical polishing.

The glassy carbon coating is prepared by applying a solution of heat treated long chain organic substance on the surface of the titanium sample. Then the item is dried and heat treated. In order to improve the adhesion of the vitreous carbon layer the heat treatment was performed at 1350 - 1400 degrees Celsius in inert environment. Titanium carbide was created during this heat treatment which is an intermediary layer between the titanium substrate and the vitreous carbon coating. In order to have better layer this procedure is repeated several times. After the heat treatment only carbon in vitreous (glassy) state remains on the surface. It has amorphous structure and its hardness is that of normal silicate glass (7 by Mohs scale). Since the coating is only carbon it is at least or even more bio-compatible than the titanium and titanium alloys.

The institute is looking for industrial and research partners for technical cooperation agreements and research cooperation agreements in order to further develop the technology and adapt it to the specific needs.
Advantages and Innovations:
- The composite material is with improved bio-compatibility and wear resistance compared to titanium only implants.
- The roughness of the surface can be controlled depending on the conditions it will be used in.
-The 3-D printing with titanium powder gives the opportunity to produce an individual implant according to the shape and the dimensions of the damaged organ.
- The glassy carbon coating adheres well to the titanium surface and it can be polished to the desired roughness. It is well tolerated by the adjacent tissues.
Stage of Development:
Under development/lab tested
IPs:
Secret Know-how

Partner sought

Type and Role of Partner Sought:
- Type of partner sought: the research team is looking for industrial and R-Y-D partners;
- Specific area of activity of the partner: partner sought related to the medical, orthopedy or related sectors; entities working on development and manufacture of composite materials and bio-compatible materials;
- Task to be performed: testing of the prototype, production, marketing or adaptation to specific needs; receiving the necessary know-how from the developer via technical cooperation agreements or research cooperation agreements are considered.

Client

Type and Size of Client:
R&D Institution
Already Engaged in Trans-National Cooperation:
Si
Languages Spoken:
Bulgarian
English
Russian

Keywords

Technology Keywords:
02007005 Composite materials
06001020 Fisioterapia, tecnología ortopédica
02001001 Impresión 3D
02007010 Metals and Alloys
02002002 Recubrimientos